|
|
cinnamaldehyde + CoA + NADP+ <=> cinnamoyl-CoA + NADPH + H+
|
1.2.1.44
cinnamoyl-CoA reductase
|
–
|
K
|
|
BRENDA:
BR29404
KEGG:
R02506
MetaCyc:
CINNAMOYL-COA-REDUCTASE-RXN
|
|
|
|
cinnamoyl-CoA + D-phenyllactate <=> Cinnamic_acid + (R)-phenyllactyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
BMK
|
|
BRENDA:
BR47452
KEGG:
R07796
MetaCyc:
2.8.3.17-RXN
|
|
|
|
malonyl-CoA + cinnamoyl-CoA + H+ <=> CoA + pinosylvin + CO2
|
2.3.1.146
pinosylvin synthase
2.3.1.95
trihydroxystilbene synthase
|
–
–
|
MK
|
|
BRENDA:
BR47494
KEGG:
R02505
MetaCyc:
PINOSYLVIN-SYNTHASE-RXN
SABIO-RK:
2432
|
|
|
|
(R)-phenyllactyl-CoA <=> cinnamoyl-CoA + H2O
|
4.2.1.175
(R)-3-(aryl)lactoyl-CoA dehydratase
|
–
|
BM
|
|
BRENDA:
BR51461
KEGG:
R12487
MetaCyc:
RXN-19883
|
|
|
|
phenylpropionyl-CoA + acceptor <=> cinnamoyl-CoA + reduced_acceptor
|
1.3.1
1.3.99.B16
|
–
–
|
M
|
|
BRENDA:
BR51544
MetaCyc:
R242-RXN
|
|
|
|
tyramine + cinnamoyl-CoA <=> H+ + cinnamoyltyramine + CoA
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
M
|
|
BRENDA:
BS320298
MetaCyc:
RXN-8713
|
|
|
|
Cinnamic_acid + CoA + ATP <=> cinnamoyl-CoA + AMP + diphosphate
|
6.2.1
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
–
|
MK
|
|
BRENDA:
BS34;
BS400329
KEGG:
R02255
MetaCyc:
RXN-2001
SABIO-RK:
12839;
2225
|
|
|
|
cinnamoyl-CoA + malonyl-CoA + H+ <=> 4-hydroxy-6-[(E)-2-phenylethenyl]-2H-pyran-2-one + CO2 + CoA
|
2.3.1.151
2,3',4,6-tetrahydroxybenzophenone synthase
2.3.1.211
bisdemethoxycurcumin synthase
2.3.1.M86
|
–
–
–
|
|
|
BRENDA:
BS419945
MetaCyc:
RXN-20964
|
|
|
|
malonyl-CoA + cinnamoyl-CoA + H+ <=> pinocembrin_chalcone + CoA + CO2
|
2.3.1
2.3.1.74
chalcone synthase
|
–
–
|
K
|
|
BRENDA:
BS454954
KEGG:
R07987
MetaCyc:
RXN-7645
SABIO-RK:
8192
|
|
|
|
cinnamoyl-CoA + 3-Phenylpropionic_acid <=> trans-cinnamate + phenylpropionyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
|
|
BRENDA:
BS354169
SABIO-RK:
14689
|
|
|
|
cinnamoyl-CoA + reduced_flavodoxin + O2 <=> 4-coumaroyl-CoA + flavin + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
K
|
|
KEGG:
R08815
|
|
|
|
H+ + cinnamoyl-CoA + 4-coumaroyl-diketide <=> (1E,6E)-1-(4-hydroxyphenyl)-7-phenylhepta-1,6-diene-3,5-dione + CoA + CO2
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-11255
|
|
|
|
cinnamoyl-CoA + glycine <=> N-cinnamoylglycine + CoA + H+
|
2.3.1.13
glycine N-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-15658
|
|
|
|
cinnamoyl-CoA + H2O <=> 3-hydroxy-3-phenylpropionyl-CoA
|
4.2.1
|
–
|
M
|
|
MetaCyc:
RXN-2002
|
|
|
|
cinnamoyl-CoA + chalcone_synthase + malonyl-CoA + H+ <=> (8E)-3,5,7-trioxo-9-phenylnon-8-enoyl-[chalcome_synthase] + CoA + CO2
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-20996
|
|
|
|
cinnamoyl-CoA + malonyl-CoA + polyketide-[acp] + H+ <=> (6E)-3,5-dioxo-7-phenylhept-6-enoyl-[styrylpyrone_synthase] + CO2 + CoA
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-20998
|
|
|
|
cinnamoyl-CoA + serotonin <=> cinnamoylserotonin + CoA + H+
|
2.3.1.M35
|
–
|
M
|
|
MetaCyc:
RXN-8712
|
|
|
|
cinnamoyl-CoA + 3-Hydroxyanthranilate <=> CoA + 3-cinnamoyloxyanthranilate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS420486
|
|
|
|
cinnamoyl-CoA + 3-Hydroxyanthranilate <=> CoA + N-cinnamoyl-3-hydroxyanthranilate
|
2.3.1.144
anthranilate N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS420487
|
|
|
|
cinnamoyl-CoA + 3-(4-hydroxyphenyl)lactate <=> CoA + 2-O-cinnamoyl-3-(4-hydroxyphenyl)lactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS420484
|
|
|
|
cinnamoyl-CoA + m-cresol <=> benzyl_(2E)-3-phenylprop-2-enoate + CoA
|
2.3.1.196
benzyl alcohol O-benzoyltransferase
|
–
|
|
|
BRENDA:
BS435400
|
|
|
|
cinnamoyl-CoA + 3-(3,4-Dihydroxyphenyl)lactate <=> CoA + 2-O-cinnamoyl-3-(3,4-dihydroxyphenyl)lactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS320510
|
|
|
|
cinnamoyl-CoA + D-phenyllactate <=> CoA + (R)-2-O-cinnamoyl-3-phenyllactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS420490
|
|
|
|
cinnamoyl-CoA + salicyl_alcohol <=> salicyl_cinnamoate + CoA
|
2.3.1.196
benzyl alcohol O-benzoyltransferase
|
–
|
|
|
BRENDA:
BS435401
|
|
|
|
cinnamoyl-CoA + cinnamoyl-diketide-N-acetylcysteamine + H2O <=> CoA + dicinnamoylmethane + N-acetylcysteamine
|
2.3.1.217
curcumin synthase
2.3.1.219
demethoxycurcumin synthase
|
–
–
|
|
|
BRENDA:
BS423125
|
|
|
|
cinnamoyl-CoA + cinnamoyl-acetyl-CoA + H2O <=> 2 CoA + dicinnamoylmethane + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS455465
|
|
|
|
cinnamoyl-CoA + H2O <=> Cinnamic_acid + CoA
|
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
|
|
|
BRENDA:
BS411877
|
|
|
|
cinnamoyl-CoA + 4-hydroxyphenylpropionic_acid <=> trans-cinnamate + dihydro-4-coumaroyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
|
|
BRENDA:
BS354170
|
|
|
|
cinnamoyl-CoA + 4-phenylbutyric_acid <=> trans-cinnamate + 4-phenylbutyryl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
|
|
BRENDA:
BS354171
|
|
|
|
cinnamoyl-CoA + phenylpropionate <=> trans-cinnamate + phenylpropionyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
|
|
BRENDA:
BS452505
|
|
|
|
cinnamoyl-CoA + putrescine <=> CoA + N-cinnamoylputrescine
|
2.3.1.138
putrescine N-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS320492
|
|
|
|
cinnamoyl-CoA + shikimate <=> CoA + 5-O-cinnamoylshikimate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS320443
|
|
|
|
cinnamoyl-CoA + anthranilate <=> CoA + N-cinnamoylanthranilate
|
2.3.1.144
anthranilate N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS420489
|
|
|
|
cinnamoyl-CoA + anthranilate <=> CoA + N-cinammoylanthranilate
|
2.3.1.144
anthranilate N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS320520
|
|
|
|
cinnamoyl-CoA + agmatine <=> CoA + cinnamoyl_agmatine
|
2.3.1.64
agmatine N4-coumaroyltransferase
|
–
|
|
|
BRENDA:
BS321164
|
|
|
|
cinnamoyl-CoA + NADPH + CO2 + H+ <=> (2S)-2-carboxy-3-phenylpropionyl-CoA + NADP+
|
1.3.1.85
crotonyl-CoA carboxylase/reductase
|
–
|
|
|
BRENDA:
BS439337
|
|
|
|
2 cinnamoyl-CoA + malonyl-CoA + H2O <=> 3 CoA + dicinnamoylmethane + 2 CO2
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS421780
|
|
|
|
cinnamoyl-CoA + malonyl-CoA <=> 5,7-dihydroxyflavanone + CoA + CO2
|
2.3.1.74
chalcone synthase
|
–
|
|
|
BRENDA:
BS321287
|
|
|
|
4-coumaroyl-CoA + cinnamoyl-CoA + malonyl-CoA + H2O <=> 3 CoA + cinnamoyl-4-coumaroyl-methane + 2 CO2
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422579
|
|
|
|
cinnamoyl-CoA + 3-hydroxybenzoate <=> CoA + 3-cinnamoyloxybenzoate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS420488
|
|